Fotografisan molekul!

[zakk]

http://news.bbc.co.uk/2/hi/science/nature/8225491.stm

Single molecule's stunning image
by Jason Palmer
Science and technology reporter, BBC News



Pentacene molecule image (IBM)
Even the bonds to the hydrogen atoms at the pentacene's periphery can be seen

The detailed chemical structure of a single molecule has been imaged for the first time, say researchers.

The physical shape of single carbon nanotubes has been outlined before, using similar techniques - but the new method even shows up chemical bonds.

Understanding structure on this scale could help in the design of many things on the molecular scale, particularly electronics or even drugs.

The IBM researchers report their findings in the journal Science.

It is the same group that in July reported the feat of measuring the charge on a single atom.


Fine tuning

In both cases, a team from IBM Research Zurich used what is known as an atomic force microscope or AFM.

Their version of the device acts like a tiny tuning fork, with one of the prongs of the fork passing incredibly close to the sample and the other farther away.

When the fork is set vibrating, the prong nearest the sample will experience a minuscule shift in the frequency of its vibration, simply because it is getting close to the molecule.

Comparing the frequencies of the two prongs gives a measure of just how close the nearer prong is, effectively mapping out the molecule's structure.

The measurement requires extremes of precision. In order to avoid the effects of stray gas molecules bounding around, or the general atomic-scale jiggling that room-temperature objects experience, the whole setup has to be kept under high vacuum and at blisteringly cold temperatures.

However, the tip of the AFM's prong is not well-defined and isn't necessarily sharp on the scale of single atoms. The effect of this bluntness is to blur the instrument's images.

The researchers have now hit on the idea of deliberately picking up just one small molecule - made of one atom of carbon and one of oxygen - with the AFM tip, forming the sharpest, most well-defined tip possible.

Their measurement of a pentacene molecule using this carbon monoxide tip shows the bonds between the carbon atoms in five linked rings, and even suggests the bonds to the hydrogen atoms at the molecule's periphery.


Tip of the iceberg

Lead author of the research Leo Gross told BBC News that the group is aiming to combine their ability to measure individual charges with the new technique, characterising molecules at a truly unprecedented level of detail.

That will help in particular in the field of "molecular electronics", a potential future for electronics in which individual molecules serve as switches and transistors.

Although the approach can trace out the ethereal bonds that connect atoms, it cannot distinguish between atoms of different types.

The team aims to use the new technique in tandem with a similar one known as scanning tunnelling microscopy - in which a tiny voltage is applied accross the sample - to determine if the two methods in combination can deduce the nature of each atom in the AFM images.

That would help the entire field of chemistry, in particular the synthetic chemistry used for drug design.

The results are of wide interest to others who study the nano-world with similar instruments. For them, implementing the same approach is as simple as picking up one of these carbon monoxide molecules with their AFM before taking a measurement.

[Meho Krljic]

Sumnjivo je to meni...

[zakk]

Pa, da je Sun objavio bilo bi i meni... ovako...

[Meho Krljic]

Ma, znam, nego, moj stari mozak ne može da tako lako prihvati činjenicu da je i ova granica probijena.

[scallop]

U mikroskopiji je uvek bio problem rezolucija. Moguće je da nove tehnologije drastično uvećavaju rezoluciju. Jebiga, Meho, znaš da mogu da ubodu jajnu ćeliju i unesu jedan spermić. I moj stari mozak pamti elektronski mikroskop kao uređaj do jaja. Mada je i meni sumnjivo, jer ovakve slike donose investicije, moguće je da će jednom snimiti atom, a neko vreme posle toga, svetove u njemu. I, eto nama "atomske princeze". Bila je jednom u "Sirius"-u priča o lažiranju da je antigravitacija rešena. Na toj priči okupili naučnike i oni navalili i posle nekoliko godina rada razočarano izvestili da su uspeli da antigravitacijom podignu neku platformu za samo jedan metar. Onda su ih obavestili da je prva priča bila lažna.

Sve je moguće, ako se pre toga ne poubijamo, jer sva vrhunska istraživanja finansiraju armije. "Za čoveka sve je oružje." napisao sam u jednoj priči.

[Meho Krljic]

Bila je jednom u "Sirius"-u priča o lažiranju da je antigravitacija rešena. Na toj priči okupili naučnike i oni navalili i posle nekoliko godina rada razočarano izvestili da su uspeli da antigravitacijom podignu neku platformu za samo jedan metar. Onda su ih obavestili da je prva priča bila lažna.

Sećam se te priče.

I, da, i za mene je elektronski mikroskop i dalje pojam "mikroskopije" a ovo mi je praktično naučna fantastika.

[zakk]

Meni je metod odličan, uopšte nema dodira sa konceptom fotografije, a liči mi na rašljarenje. Prinesu nešto molekulu i kupe vibracije. Slika mi je zanimljiva jer se ustvari samo veze između atoma i vide, i tamo gde je molekul (ajdakažemtako) aktivniji, slika daje shvatljivu predstavu o tome. Time je blisko shematskom predstavljanju jedinjenja koje se standardno koristi u hemiji i toj simboličkoj predstavi koju sam imao. I sad to stvarno tako može da se opaža...

Što se skeniranja atoma tiče, nešto ne znam kako će to da se desi, ali voleo bih da vidim i to. Sve hoću da vidim!

Bila je jednom u "Sirius"-u priča o lažiranju da je antigravitacija rešena. Na toj priči okupili naučnike i oni navalili i posle nekoliko godina rada razočarano izvestili da su uspeli da antigravitacijom podignu neku platformu za samo jedan metar. Onda su ih obavestili da je prva priča bila lažna.

Sećam se te priče.

Jel to ono sa dva naučnika na pecanju? Kad jedan pije pivo a drugi gleda u neke virove u vodi pa skonta šta treba da radi?

[scallop]

Nije.

Pokupi vojska naučnike i prikažu im film sa čovekom koji na leđima nosi mali uređaj i njime, bez pogona, uzleti na visinu od 50 metara. Onda se on strmekne i pogine. Objasne naučnicima da je čova demonstrirao svoj uređaj. Odu potom u njegovu kuću da traže podatke, a tamo sva naučna literatura, a pored nje i paranauka, ezoterija, okultna literatura. Nema za šta da se uhvatiš. Konkretnih podataka nema. Vojska bacila durdubaka, a oni se upecali. Zatvore ih da na miru rade i samo jedan sumnja sve vreme da su ih podjebali... Ostalo sam već napisao u postu.

I ova slika može da bude nešto slično.

[zakk]

Aha, sećam se...

Pa nek bude i to, samo nek se napravi. Ja i dalje hoću svoj ranac za letenje.